全文获取类型
收费全文 | 26149篇 |
免费 | 5208篇 |
国内免费 | 5388篇 |
专业分类
化学 | 19376篇 |
晶体学 | 508篇 |
力学 | 1720篇 |
综合类 | 571篇 |
数学 | 3384篇 |
物理学 | 11186篇 |
出版年
2024年 | 29篇 |
2023年 | 408篇 |
2022年 | 651篇 |
2021年 | 811篇 |
2020年 | 1051篇 |
2019年 | 1033篇 |
2018年 | 945篇 |
2017年 | 958篇 |
2016年 | 1173篇 |
2015年 | 1336篇 |
2014年 | 1597篇 |
2013年 | 2030篇 |
2012年 | 2335篇 |
2011年 | 2516篇 |
2010年 | 1954篇 |
2009年 | 2008篇 |
2008年 | 2201篇 |
2007年 | 1899篇 |
2006年 | 1785篇 |
2005年 | 1558篇 |
2004年 | 1290篇 |
2003年 | 908篇 |
2002年 | 923篇 |
2001年 | 869篇 |
2000年 | 725篇 |
1999年 | 585篇 |
1998年 | 421篇 |
1997年 | 395篇 |
1996年 | 355篇 |
1995年 | 303篇 |
1994年 | 286篇 |
1993年 | 242篇 |
1992年 | 160篇 |
1991年 | 161篇 |
1990年 | 155篇 |
1989年 | 112篇 |
1988年 | 111篇 |
1987年 | 94篇 |
1986年 | 67篇 |
1985年 | 50篇 |
1984年 | 52篇 |
1983年 | 47篇 |
1982年 | 42篇 |
1981年 | 33篇 |
1980年 | 23篇 |
1979年 | 11篇 |
1976年 | 6篇 |
1975年 | 8篇 |
1971年 | 4篇 |
1959年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
41.
Bowen Yang Feng Cai Shuai Huang Prof. Dr. Haifeng Yu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(10):4064-4071
Imprinting nanopatterns on flexible substrates has diverse applications in advanced fabrication. However, the traditional thermal nanoimprint lithography (T-NIL) often causes shrinkage upon cooling. Here, a simple yet versatile method is introduced to fabricate multiple nanopatterns on a flexible substrate coated with an azopolymer by combining athermal nanoimprint lithography (AT-NIL) and photolithography. The azopolymer has various mechanical properties upon photoirradiation: 1) phototunable glass-transition temperatures (Tg) and concomitantly photoinduced switch from glassy plastic to viscoplastic polymer; 2) prominent modulation of viscoplasticity under light illumination at different wavelengths. Regionally selective multiple nanopatterns are conveniently fabricated, presenting angle-dependent structural color images on poly(ethylene terephthalate) (PET) substrates. The flexible, athermal and multiple nanopatterning method has the potential for on-demand fabrication of complex nanopatterns. 相似文献
42.
Acta Mechanica Sinica - This paper investigates the flux-pinning-induced stress behaviors in a long superconducting slab with a central cuboid hole. The distribution of flux density is analytically... 相似文献
43.
Dr. Xiang Hao Kaixiang Yang Hairong Wang Prof. Feng Peng Prof. Haiyang Yang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(11):4344-4349
Non-Newtonian fluids are ubiquitous in daily life and industrial applications. Herein, we report an intelligent fluidic system integrating two distinct non-Newtonian rheological properties mediated by an autocatalytic enzyme reaction. Associative polyelectrolytes bearing a small amount of ionic and alkyl groups are engineered: by carefully balancing the charge density and the hydrophobic effect, the polymer solutions demonstrate a unique shear thickening property at low pH while shear thinning at high pH. The urea-urease clock reaction is utilized to program a feedback-induced pH change, leading to a strong upturn of the nonlinear viscoelastic properties. As long as the chemical fuel is supplied, two distinct non-Newtonian states can be achieved with a tunable lifetime span. As a proof of concept, we demonstrate how the physical energy-driven nonequilibrium properties can be manipulated by a chemical-fueled process. 相似文献
44.
In the paper, the authors establish several integral representations for the generating functions of the large and little Schröder numbers and for the large and little Schröder numbers. 相似文献
45.
Zhiyong Chen Mengmeng Wang Yuanyuan Yang Xiaomin Cui Jing Hu Ye Li Feng Zhao 《Biomedical chromatography : BMC》2020,34(2):e4726
Multicompound determination for the quality control of traditional Chinese medicine (TCM) may often be inadequate, since these compounds may not be associated with, or fully represent, the clinical effects of TCM. Moreover, the individual contributions of each constituent to the pharmacological effect are often not considered. In China, Porana sinensis is widely used as a substitute for Erycibe sources to treat joint pain and rheumatoid arthritis. The existing quality control methods for P. sinensis neither consider the individual contributions of various compounds nor control the actual quality associated with different clinical efficacies. In the present study, a novel efficacy-oriented approach, named the effect-constituent index (ECI), was established for P. sinensis. Analyses of the spectrum–effect relationship and components in rat plasma were conducted to systematically and scientifically select quality markers. Quantitative analysis of multicomponents via a single marker method was introduced to enhance the practical application value of the established ECI. The established ECI shows a good ability to distinguish and predict the bioeffect-based quality of P. sinensis. The present study also provides a reference for the establishment and application of ECI as a quality control method for TCMs. 相似文献
46.
Meccanica - In this work, a bond-based peridynamic de-icing model has been developed to simulate the thermo-mechanical ice removal process of frozen structures. In the proposed numerical method,... 相似文献
47.
Nonlinear Dynamics - In this paper, a class of switched fractional-order continuous-time systems with order $$0<\alpha <1$$ is investigated. First, an interesting property of... 相似文献
48.
相干anti-Stokes Raman散射(coherent anti-Stokes Raman scattering,CARS)技术作为一种非接触测量手段,已广泛应用于多种发动机模型燃烧室温度测量及地面试验.然而,目前的工作主要集中在稳态燃烧场温度的测量,缺乏用高分辨率的单脉冲来测量瞬变的燃烧火焰温度及组分浓度的研究.基于CARS理论,结合多参数拟合算法,开发了基于MATLAB的CARS光谱计算和拟合程序CARSCF;利用McKenna平面火焰炉在不同工况下进行了温度测量,并与DLR测量结果进行对比,结果显示开发的CARSCF具有较高的测量重复性和准确性;最后将CARS技术应用于测量超燃冲压发动机点火过程中的温度测量,获取了点火过程中的温度.结果显示,在来流Mach数为3的条件下,H2/air点火过程中温度呈现急剧上升然后缓慢下降,而CARS信号则呈现急剧上升然后急剧下降随后又缓慢上升的趋势,并且在点火过程中最高温度为1 511 K. 相似文献
49.
Meccanica - This paper introduces an analytical approach to optimize the textured bearing with cavitation to improve the load support. For this purpose, a grooved parallel slider bearing is... 相似文献
50.
Hongling Yu Heyong Wang Galia Pozina Chunyang Yin Xiao-Ke Liu Feng Gao 《Chemical science》2020,11(41):11338
Metal halide perovskites have demonstrated impressive properties for achieving efficient monochromatic light-emitting diodes. However, the development of white perovskite light-emitting diodes (PeLEDs) remains a big challenge. Here, we demonstrate a single-emissive-layer all-perovskite white PeLED using a mixed halide perovskite film as the emissive layer. The perovskite film consists of separated mixed halide perovskite phases with blue and red emissions, which are beneficial for suppressing halide anion exchange and preventing charge transfer. As a result, the white PeLED shows balanced white light emission with Commission Internationale de L''Eclairage coordinates of (0.33, 0.33). In addition, we find that the achievement of white light emission from mixed halide perovskites strongly depends on effective modulation of the halide salt precursors, especially lead bromide and benzamidine hydrochloride in our case. Our work provides very useful guidelines for realizing single-emissive-layer all-perovskite white PeLEDs based on mixed halide perovskites, which will spur the development of high-performance white PeLEDs.We demonstrated a single-emissive-layer all-perovskite white light-emitting diode based on a mixed halide perovskite film. 相似文献